I can only try and reply from my own experiences - as (a) a recent college student and (b) a psychology major.
I never procrastinated when I was younger. Never. Mom or Grandpa or Mrs. Stilleins was always there to pester me about whether I had finished my work. Being a terrible liar, I couldn't convince them that I had, so I had no room to procrastinate. When I got to college, of course, there were no grown-ups breathing down my neck to get all my stuff done. So what did I do?
I did NOT procrastinate.
I believe that procrastination is a learned response. In my case, I learned that if I put everything to the last minute, doom will ensue and I will die a bloody violent death. Was this ever proved to me? Of course not - because I was never allowed to put anything off to the last minute and then absorb the consequences. The process is called negative punishment: adverse circumstances are avoided by behaving well/properly/whatever. The day that misbehaving takes place and adverse circumstances never happen, a revolution occurs.
My first all-nighter of my life was 2/3 of the way through my junior year, and it was mostly by accident. I was writing a linguistics paper and had completely finished the analysis, notes, writeup, even the intro/conclusion bits, which were the worst. I still hadn't spliced everything together, which I decided was as easy as Ctrl+C & Ctrl+V. But I hadn't realized that inserting 278 different IPA characters, by hand, would take so long. Then I realized, at 2 AM (the paper was due by 8AM same day), that I was editing the a former draft. Should I edit this horrible draft or begin inserting characters in the newer, still-mostly-disordered, newer draft?
I typed in the very last character into the inferior draft at 5:15 in the morning. Printed; flopped into bed; set an alarm for 7:30 to catch a last-minute shuttle to campus. As it was, I ran up the four flights to the student service desk, got my paper time-stamped, and slid it under my professor's door at 7:57. I knew that my life would begin to unravel after my professor gave me a fat, shining, blood-red-inked F on that paper, destroying my delicate GPA with one deft stab.
I got an A+. It saved my grade in the class.
Since then I have developed such wonderful habits as being late for everything (as opposed to perfectly punctual), forgetting important documents for presentations, paying bills late, nearly starving everyone from lack of planning during dinner parties, etc.
The worst part is that I think the process is permanent. If I had gotten an F on that paper, I would have cried and wailed and had a big fat baby fit...but I'm sure I wouldn't have learned anything about procrastination from it. At best I'd hate myself and continue to put things off.
Can you remember your first major procrastinatory experience? When was it - how old were you? What were the terms (e.g., accidental, TV vs. homework, all-nighter, etc)? Do you think it could have been the stepping stone on a spiral into perpetual procrastination?