Hi AB,
What makes you think that this is a trait "selected" for? I think usually arguing about evolution of behaviors in isolation is sketchy science. The brain and personality are pretty complex/interdependent. Introverted people have interesting qualities which might result in selection for introversion, etc. Maybe every society from the dawn of time has needed good accountants. Also, society needs explorers, travelers, captains etc who are willing to leave their family/friends and voyage far away to scout things out and bring back treasure.
Was the 20% figure your estimate? I'd be surprised if 20% of the population were reclusive in a static sense. People go through periods in their lives where they are more social and periods where they are more withdrawn. Those folks who don't talk to their neighbors may have had a wild social life, partners, kids in their twenties. Maybe now they are enjoying time to themselves.
That said society now is also a lot more isolating. I bet a lot more people qualify as "loners" now than in previous generations, as all their friends are spread across the country, they don't have an automatic huge clan to be part of, etc.